{"created":"2023-07-25T10:31:57.215972+00:00","id":4370,"links":{},"metadata":{"_buckets":{"deposit":"62b5bd87-ace7-4d40-9e0e-6716391c2162"},"_deposit":{"created_by":4,"id":"4370","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"4370"},"status":"published"},"_oai":{"id":"oai:hbg.repo.nii.ac.jp:00004370","sets":["27:829"]},"author_link":["19527","19528","19529","19530","19531","19532","19533","19534","19535","19536"],"item_10004_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1984","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"214","bibliographicPageStart":"203","bibliographic_titles":[{"bibliographic_title":"Journal of the Chemical Society. Perkin transactions 1"}]}]},"item_10004_description_19":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10004_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"　The structures and absolute configurations of the two sesquiterpene aldehydes, (–)-isobicyclogermacrenal (1) and (–)-lepidozenal (2), which were isolated from the liverwort Lepidozia vitrea, have been determined on the basis of chemical and spectroscopic evidence to be (6R,7S)-6,11-cyclogermacra-1(10)-E,4E-dien-14-al and (6R,7S)-lepidoza-1 (10)E,4E-dien-14-al, consisting of the cis- and trans-10,3-bicyclic ring systems. The structure of the former (1) has been confirmed by a single-crystal X-ray analysis of its hydroxy derivative (7). The molecular conformations, biogenetical features, and biological activity are also described.","subitem_description_type":"Abstract"}]},"item_10004_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Chemical Society"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Matsuo, Akihiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19527","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nozaki, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19528","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kubota, Naoji","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19529","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Uto, Seiryû","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19530","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nakayama, Mitsuru","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19531","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Matsuo, Akihiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19532","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nozaki, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19533","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kubota, Naoji","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19534","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Uto, Seiryû","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19535","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nakayama, Mitsuru","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19536","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-05-29"}],"displaytype":"detail","filename":"matsuo_akihiko_098.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"matsuo_akihiko_098.pdf","objectType":"fulltext","url":"https://hbg.repo.nii.ac.jp/record/4370/files/matsuo_akihiko_098.pdf"},"version_id":"e23a8efb-7373-41d3-ab70-9592896e686d"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Structures and conformations of (–)-isobicyclogermacrenal and (–)-lepidozenal, two key sesquiterpenoids of the cis- and trans-10,3-bicyclic ring systems, from the liverwort Lepidozia vitrea : X-ray crystal structure analysis of the hydroxy derivative of (–)-isobicyclogermacrenal","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Structures and conformations of (–)-isobicyclogermacrenal and (–)-lepidozenal, two key sesquiterpenoids of the cis- and trans-10,3-bicyclic ring systems, from the liverwort Lepidozia vitrea : X-ray crystal structure analysis of the hydroxy derivative of (–)-isobicyclogermacrenal","subitem_title_language":"en"}]},"item_type_id":"10004","owner":"4","path":["829"],"pubdate":{"attribute_name":"公開日","attribute_value":"2023-03-15"},"publish_date":"2023-03-15","publish_status":"0","recid":"4370","relation_version_is_last":true,"title":["Structures and conformations of (–)-isobicyclogermacrenal and (–)-lepidozenal, two key sesquiterpenoids of the cis- and trans-10,3-bicyclic ring systems, from the liverwort Lepidozia vitrea : X-ray crystal structure analysis of the hydroxy derivative of (–)-isobicyclogermacrenal"],"weko_creator_id":"4","weko_shared_id":-1},"updated":"2023-09-13T03:23:27.220165+00:00"}