{"created":"2023-07-25T10:31:57.994975+00:00","id":4384,"links":{},"metadata":{"_buckets":{"deposit":"ae929e37-6f12-4e6c-a47e-3250501d412f"},"_deposit":{"created_by":4,"id":"4384","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"4384"},"status":"published"},"_oai":{"id":"oai:hbg.repo.nii.ac.jp:00004384","sets":["27:820"]},"author_link":["19647","19648","19649","19650","19651","19652","19653","19654","19655","19656","19657","19658","19659","19660","19661","19662"],"item_10004_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1982","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"8","bibliographicPageEnd":"1146","bibliographicPageStart":"1143","bibliographicVolumeNumber":"11","bibliographic_titles":[{"bibliographic_title":"Chemistry Letters"}]}]},"item_10004_description_19":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10004_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"　(±)-Vitrenal (1), a sesquiterpene aldehyde with a novel vitrane skeleton, was synthesized from a monoterpene piperitenone (2) by 12-step reactions in ca. 7% overall yield. 2-Formyl-isocarane, derived from 2 via (±)-isocaran-2-one was allylated stereospecifically and, after protection of the formyl group, the allyl chain was modified to a 4-methoxy-3-butenyl group. Acid treatment of the masked dialdehydic intermediate yielded 1 by concomitant deprotection and aldol condensation.","subitem_description_type":"Abstract"}]},"item_10004_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Chemical Society of Japan"}]},"item_10004_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00603318","subitem_source_identifier_type":"NCID"}]},"item_10004_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03667022","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Magari, Hideaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19647","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hirota, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19648","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Takahashi, Takeyoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19649","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Matsuo, Akihiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19650","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Uto, Seiryu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19651","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nozaki, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19652","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nakayama, Mitsuru","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19653","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hayashi, Shuichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19654","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Magari, Hideaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19655","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hirota, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19656","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Takahashi, Takeyoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19657","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Matsuo, Akihiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19658","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Uto, Seiryu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19659","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nozaki, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19660","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nakayama, Mitsuru","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19661","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hayashi, Shuichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19662","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-05-29"}],"displaytype":"detail","filename":"matsuo_akihiko_090.pdf","filesize":[{"value":"283.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"matsuo_akihiko_090.pdf","objectType":"fulltext","url":"https://hbg.repo.nii.ac.jp/record/4384/files/matsuo_akihiko_090.pdf"},"version_id":"1f01e4cb-4461-4f01-be78-c88357780d66"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"SYNTHESIS OF (±)-VITRENAL","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"SYNTHESIS OF (±)-VITRENAL","subitem_title_language":"en"}]},"item_type_id":"10004","owner":"4","path":["820"],"pubdate":{"attribute_name":"公開日","attribute_value":"2023-03-15"},"publish_date":"2023-03-15","publish_status":"0","recid":"4384","relation_version_is_last":true,"title":["SYNTHESIS OF (±)-VITRENAL"],"weko_creator_id":"4","weko_shared_id":-1},"updated":"2023-09-13T02:50:26.466752+00:00"}