| Item type |
一般雑誌記事 / Article(1) |
| 公開日 |
2023-03-15 |
| タイトル |
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タイトル |
Structures and conformations of (–)-isobicyclogermacrenal and (–)-lepidozenal, two key sesquiterpenoids of the cis- and trans-10,3-bicyclic ring systems, from the liverwort Lepidozia vitrea : X-ray crystal structure analysis of the hydroxy derivative of (–)-isobicyclogermacrenal |
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言語 |
en |
| 言語 |
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言語 |
eng |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
article |
| 著者 |
Matsuo, Akihiko
Nozaki, Hiroshi
Kubota, Naoji
Uto, Seiryû
Nakayama, Mitsuru
Matsuo, Akihiko
Nozaki, Hiroshi
Kubota, Naoji
Uto, Seiryû
Nakayama, Mitsuru
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| 抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
The structures and absolute configurations of the two sesquiterpene aldehydes, (–)-isobicyclogermacrenal (1) and (–)-lepidozenal (2), which were isolated from the liverwort Lepidozia vitrea, have been determined on the basis of chemical and spectroscopic evidence to be (6R,7S)-6,11-cyclogermacra-1(10)-E,4E-dien-14-al and (6R,7S)-lepidoza-1 (10)E,4E-dien-14-al, consisting of the cis- and trans-10,3-bicyclic ring systems. The structure of the former (1) has been confirmed by a single-crystal X-ray analysis of its hydroxy derivative (7). The molecular conformations, biogenetical features, and biological activity are also described. |
| 書誌情報 |
Journal of the Chemical Society. Perkin transactions 1
p. 203-214,
発行日 1984
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| 出版者 |
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出版者 |
Chemical Society |
| フォーマット |
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内容記述タイプ |
Other |
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内容記述 |
application/pdf |
matsuo_akihiko_098.pdf (1.3 MB)
